4-Vinylbenzyl chloride

4-Vinylbenzyl chloride
Names
Other names
VBC, α-chloromethylstyrene
Identifiers
1592-20-7
3D model (Jmol) Interactive image
ChemSpider 66739
EC Number 250-005-9
PubChem 74126
Properties
C9H9Cl
Molar mass 152.62
Appearance colorless liquid
Density 1.083
Boiling point 229 °C (444 °F; 502 K)
Hazards
Main hazards alkylating agent
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

4-Vinylbenzyl chloride is an organic compound with the formula ClCH2C6H4CH=CH2. It is a bifunctional molecule, featuring both vinyl and a benzylic chloride functional groups. It is a colorless liquid that is typically stored with a stabilizer to suppress polymerization.

In combination with styrene, vinylbenzyl chloride is used as a comonomer in the production of chloromethylated polystyrene.[1] It is produced by the chlorination of vinyltoluene. Often vinyltoluene consists of a mixture of 3- and 4-vinyl isomers, in which case the vinylbenzyl chloride will also be produced as a mixture of isomers.[2]

References

  1. Montheard, Jean Pierre; Jegat, Corinne; Camps, Marcel "Vinylbenzylchloride (chloromethylstyrene), polymers, and copolymers. Recent reactions and applications" Journal of Macromolecular Science, Reviews in Macromolecular Chemistry and Physics 1999, volume C39, pp. 135-174.
  2. Denis H. James; William M. Castor (2007), "Styrene", Ullmann's Encyclopedia of Industrial Chemistry (7th ed.), Wiley, p. 1, doi:10.1002/14356007.a25_329.pub2
This article is issued from Wikipedia - version of the 10/31/2016. The text is available under the Creative Commons Attribution/Share Alike but additional terms may apply for the media files.