Konstantinos Fostiropoulos

Konstantinos Fostiropoulos
Born (1960-06-20) 20 June 1960
Κρύα Βρύση, Πέλλα, Greece
Residence Berlin, Germany
Nationality Greek
Fields
Institutions
Alma mater

Thesis "C60 - a new form of carbon" (1989-1992)
Known for Buckminsterfullerene, organic photovoltaics

Konstantinos Fostiropoulos is a Greek physicist who has been working in Germany in the areas nano-materials, solid-state physics, molecular physics, astrophysics, and thermodynamics. Since 2003 he has been founder and head of the Organic Solar Cells Group at the Institute Heterogeneous Materials Systems within the Helmholtz-Zentrum Berlin. His scientific works include novel energy materials and photovoltaic device concepts, carbon clusters in the Interstellar Medium, and intermolecular forces of real gases.

In 1989 Fostiropoulos was the first to synthesize C60, a molecular carbon modification, in preparative amounts[1][2] by a specifically developed vacuum process. After the discovery of the molecule 1985 by Kroto et al.,[3] Fostiropoulos' work contributed essentially to the establishment of fundamental fullerene research as well as its applications.
In 2001/2002 he presented a bilayer heterojunction concept for Organic Photovoltaic devices applying vacuum processes for the formation of a molecular absorber layer consisting of Zn-phthalocyanine and C60 molecules achieving a then world record power conversion efficiency of 2.5% [4] for such devices.

Moreover, he has been an expert in distance education who demonstrated even back in 1999 an experimental low band width connectivity transatlantic internet teaching platform.[5]

Personal life

Migration

Fostiropoulos was born 20 June 1960 in Κρύα Βρύση, Πέλλα, Greece, to Anastasios Fostiropoulos and Lemonia Fostiropoulou (née Atmatzidou) the second of three children (Niko, Kosta, Eleni). In 1961 his father emigrated to Mannheim, Germany where later his wife followed with their two sons when Fostiropoulos was four years old. There, five years later his sister Eleni was born. Until they retired his parents Anastasios and Lemonia had been working as labourer and cleaner, respectively. In 2015 they re-immigrated in Greece, together with his sister Eleni and her family. His brother Niko has been elected town counsellor in Karlsruhe, Germany and is owner of the centre for further education alfatraining.

Marriage

During his time as research fellow at the former GMD - German National Research Center for IT in Sankt Augustin near Bonn Fostiropoulos' relationship to his colleague Simone Lahme, a web-designer and specialist for e-learning, began on the occasion of the Total Solar Eclipse on 11 August 1999, which they had been observing together in Karlsruhe. They married in 2004[6] and have two children, Timon and Melina.

Education

"Alte Feuerwache" -
Landmark of Mannheim-Neckarstadt

In his early years in Mannheim Fostiropoulos graduated from German basic primary Hilda-Schule and secondary Kurpfalzgymnasium Mannheim as well as from Greek afternoon primary school. Moreover, he graduated from the Städtische Musikschule Mannheim where he had attended as a guitarist the pick instruments class of Takashi Ochi.

Fostiropoulos studied physics at the nearby Heidelberg University where he was, particularly, intrigued by the Grand Unified Theory, laser physics and molecular physics. He obtained his Diploma after having joined the research group of Bernhard Schramm, Institute of Physical Chemistry. In February 1989 he attended the "Dust Group" of Hugo Fechtig, Department Cosmophysics at Max Planck Institute for Nuclear Physics, where he worked as doctoral candidate on his thesis "C60 - eine neue Form des Kohlenstoffs". In February 1992 he received his Ph.D. from Heidelberg University.

Because of his family's financial constraints he had been working in varies jobs during his studies: as classical guitar instructor at Mannheimer Abendakademie, sound engineer for simultaneous translation at Ellerbrock Konferenztechnik, and teaching assistant of Physical Chemistry at Heidelberg University.

First scientific career - "fundamental research"

From 1986-88 Fostiropoulos was investigating effects of intermolecular forces in real gases at the Institute of Physical Chemistry, Heidelberg University. One focus was to study the thermodynamical properties of freons in order to substitute them by environmentally compatible substances in refrigerator units.

The historical origin of carbon lamps (1802 - 1960s)

carbon lamps by arc (1), contact arc (2) or by resistive heating (3)  
A well-known method to generate and study atoms, small clusters and big agglomerates (dust particles) of conductive materials (e.g. graphite, metals...) is to thermally evaporate them from rigid rods under low pressure conditions or vacuum. Thereby, either an arc or contact arc is ignited between two such rods (electrodes), or resistive heating of one rod is applied for its electrical evaporation. Particularly, in the 19. century the element carbon had been studied in detail to develop non-degradable graphite electrodes for intensive carbon arc lamp spot light applications (e.g. in cinema projectors). They were invented by Humphry Davy in 1802 and had been in use for more than a hundred years. In the 1960s those methods were revived in order to study the chemistry of carbon vapours in rare-gas atmospheres (He, Ar...), e.g. by William Weltner jr.[7]

The Heidelberg experiments

Beautiful Heidelberg

In September 1987 a young volunteering student, Bernd Wagner,[8] joint the "Dust Group" of astrophysicist Hugo Fechtig at Max Planck Institute for Nuclear Physics for a few weeks. There, under the supervision of Fechtig's assistant Wolfgang Krätschmer Wagner had been performing such carbon vapour experiments using the contact arc method (2) when he accidentally changed the pressure conditions. As a result, he received traces of carbon dust with additional weak IR absorption features unknown to him. However, the result was not considered further, when Wagner left, but was deemed "impurities from pump oil"[9] or simply "junk".[10]
In January 1989 Fostiropoulos joined Fechtig's group, where he picked up the "accidental" experiment. After a few weeks assessment period he decided to study as part of his Ph.D. the three kind of thermal evaporation processes in detail and, subsequently, he developed new process parameters for each. Accordingly, in 1989 Fostiropoulos was the first to synthesize C60 the first molecular carbon modification[1][2] applying initially a contact arc process (2) with specific experimental conditions for fast electrode degradation, hence, accelerated carbon evaporation. Moreover, he developed a method to sinter graphite rods from commercially available "amorphous" 13C carbon dust. Applying a resistive heating process (3) and using such "isotopic" graphite rods, a few days before New Year's Eve 1989, he synthesized for the first time an unusual material which contained an exotic species: "isotopic" 13C60,[11] From that he, casually, proved the existence of an all-carbon molecule with icosahedral "platonic" symmetry and truncated icosahedron "archimedean" shape predicted by Kroto et al. 1985: C60 "Buckminsterfullerene"![3]

C60 publication activities triggered by the Heidelberg experiments 1990[12]

In his effort to push the production yield further he then focused his research on the simple arc method (1) that culminated in 1990 in a yield of > 1 gram per day[2] achieved by a robust and highly efficient arc process. As the fullerene material, however, was still embedded in the generated soot Fostiropoulos developed two possible extraction methods, either by applying thermal evaporation to expel the molecular species C60, C70... from the soot under vacuum conditions or by dispersing the soot in benzene where only fullerenes dissolve. The extracted powder of this "natural" pure fullerene mixture was analyzed by optical (UV to IR) as well as mass spectroscopy where also the "American football" shaped C70 was found. From the powder he could grow for the first time ultra-thin C60 films by vacuum thermal evaporation and watch the formation of hexagonal crystals from the "wine-red" benzene solution. From subsequent thin film chromatography studies[13] the wine-red colour turned out to originate from the 10% C70 fraction in the natural fullerene mixture. The mass density of the novel Carbon crystals was determined experimentally as well as theoretically using data from a TEM crystal analysis measured for the first time in collaboration with Werner Kühlbrandt,[14] EMBL Heidelberg, where the van der Waals diameter of the molecular "football" was determined: dC60= 1.0 nm. In collaboration with Hans Hermann Eysel, Institute of Inorganic Chemistry, Heidelberg University, for the first time Raman spectra of C60 have been measured.

Université Pierre-et-Marie-Curie Paris VI campus de Jussieu

Beginning of 1991 Fostiropoulos was invited to visit the research group of astrophysicist Alain Léger at Paris University VI for two months where they performed matrix isolation spectroscopy on C−
60 and C+
60 ions in cold Ne matrices in order to measure their optical absorptions under quasi-space conditions. Particularly, the positive ion was a potential candidate for the carrier of Diffuse Interstellar Bands as discussed independently by Harry Kroto 1987.[15] An immediate proposal in cooperation with Fostiropoulos submitted by Alain Léger and Louis Le Sergeant d'Hendecourt for one week observing time at the Canada-France Hawaii Telescope in order to search for C+
60 fingerprints in the interstellar medium had been accepted. However, subsequently, the MPI in Heidelberg rejected its, hence, Fostiropoulos' participation in the search for C+
60 in the interstellar medium.
After all, in 1994 the hunt for the spectral fingerprints of the interstellar football provided a first paper where Bernard Foing and Pascale Ehrenfreund identified the molecule as carrier of two diffuse interstellar bands.[16] Their estimation has been confirmed in many other papers that roughly 0.1% (!) of all carbon in the interstellar medium exists as "C60 - a new form of carbon".

With his results on the synthesis, extraction and characterization of fullerenes published 1990 in NATURE[17] (Web of Science: 5.716 citations) and some astrophysical aspects of ionized and hydrogenated C60 he found in his data Fostiropoulos hastily completed his Ph.D. thesis by the end of 1991[18] that has been triggering waves of publications worldwide since then.[19]

Invited Talks (1991-1993)

Institution Host 
15 Jan 1991 Université Pierre et Marie Curie, Paris Alain Léger, Groupe de physique des solides
20-30 Oct 1991 Centre Majorana Erice, Sicilia Summer School: "Origin of life"
January 1992 ETH Zurich Hans-Ude Nissen, Institute for Solid State Physics
25 Mar 1992 National Nuclear Research Center Karlsruhe Reinhard von Ammon, Institute of hot chemistry
9 May 1992 Institut Fresenius, Wiesbaden
26 May 1992 Tübingen University Andreas Hirsch
2 Jun 1992 Konstanz University Paul Leiderer, Klaus Dransfeld, Surface and Low Temperature Physics
23-26 Jun 1992 Adriatico Research Conference, Trieste "Clusters and Fullerenes"
April 1993 Göttingen University Klaus Fricke, Göttingen Observatory
7-10 Oct 1993 Jena University Thomas Henning, Max Planck Group: "Dust in star forming regions"

Anecdotes

Few months after Fostiropoulos began his research on the strange soot Krätschmer recommended to stop this vain undertaking and focus on astrophysically relevant carbon clusters like C2, C3, C4...[20] Therefore, Fostiropoulos decided to waste 18 months (= Ph.D. halftime) playing football and if there would be no positive result he would switch to "reasonable" carbon clusters. After 12 months intensive research, however, he succeeded to prove the existence of the all-carbon molecule with icosahedral symmetry (isotopic 13C60) and after 15 months (around 1 May 1990) he had optimized the synthesis yield and accomplished to extract the fullerene powder from the soot. After 18 months they submitted their NATURE publication.[17]

In summer 1990 during a cooperation at the Heidelberg University on Raman spectroscopy to verify the hypothetical "football" structure of the molecule one of the partners expressed carefully his concerns: "hopefully it is not a cold fusion ;-)" referring to the most famous erratum at that time published by Martin Fleischmann et al. 1989.

The NATURE publication[17] had been accepted 7 September 1990. On this occasion Fostiropoulos had the opportunity to meet and discuss with Rick Smalley the later Nobel Laureate (1996) on a conference when he invited him and Krätschmer "to come to Konstanz and use a fraction of Smalley's lecture time" (12 September 1990) where Krätschmer reported their break-through in preparation of large amounts of fullerenes.[21] A few days later Harry Kroto, also Nobei Laureate (1996), and his wife Margaret unexpectedly visited the Heidelberg scientists on their way back from a conference in Yugoslavia. Kroto[22] presented Fostiropoulos and Krätschmer with a bottle of "red wine" Châteauneuf-du-Pape 1985. On the last working day before Christmas 1990 Fostiropoulos and Krätschmer enjoyed Kroto's wine at the Max Planck Institute in Heidelberg.

On the occasion of Fostiropoulos' final Ph.D. thesis presentation to the Department of Cosmophysics of the institute he invited young Bernd Wagner[8] to the talk as his guest in order to meet him in person and introduce him to the department as the lucky guy who kicked off the Heidelberg part of the C60 story.

After the abortion of his first scientific career by the end of 1993 Fostiropoulos worked in various jobs from 1994 till 1997 when he joined the Hellenic Army to perform his military service.

Second scientific career - "applications"

Schloss Birlinghoven - GMD headquarters in Sankt Augustin near Bonn

For his come-back to fullerene research Fostiropoulos' references have been Nobel Laureate Harry Kroto and Robert Schlögl.

IT applications: distance education

In 1998 Fostiropoulos resumed scientific activities joining the Institute for Media Communication at the former GMD - German National Research Centre for Information Technology for three years where he participated in IT projects in the field of distance education. He had been running a JAVA based platform for regular lectures from Schloss Birlinghoven (GMD headquarters) to the Geneva University. For the first time internet connectivity including satellite transmission (EUTELSAT) was used to set-up a transatlantic teaching network between the then CAPE consortium of the University of Pennsylvania, via GMD, to ICI at Bucharest University as well as the Bulgarian Academy of Sciences in Sofia demonstrating transatlantic tele-teaching capability with video-conference and lecture notes through low bandwidth internet applications.[5]

Fullerene applications: organic solar cells

The research field of organic solar cells (OSC) is divided in two parts. Most scientist use wet chemical methods applying polymer materials as one of the two components to form the absorber layer of the devices, whereas the use of small absorber molecules deposited by vacuum thermal evaporation techniques is rather a niche of the field. However, in both concepts C60 is the other important component of the absorber because of its extraordinary electron acceptor properties. In 2002 Fostiropoulos presented a bi-layer heterojunction absorber concept with Zn-phthalocyanine and C60 molecules as donor and acceptor materials, respectively. Thus, he achieved a power conversion efficiency of η=2.5% which was the world record for small molecules OSC at that time catching up a similar record of polymer solar cells (2001-2003 by Brabec, Sariciftci, Hummelen 2001[23][24]). These two records had been at the beginning of a generous funding period in Germany for the field of organic photovoltaics which lasted more than a decade.

A year later (Dec 2003) Fostiropoulos founded the Organic Solar Cells Group at the Institute Heterogeneous Material Systems within the Helmholtz-Zentrum Berlin (the then Hahn-Meitner-Institut). He was awarded more than two million € mainly from the Federal Ministries BMU and BMBF, to a minor degree also by the Solar Energy Division at HMI to build and equip laboratories for the development of vacuum preparation techniques for ultra-thin organic layer systems. Since then, the two ministries have been directly financing the Organic Solar Cells Group activities by ≈ 4 M€ additional project funding.

Teaching and consultancy

Aristotle University of Thessaloniki, "ΜΟΥΣΕΣ ΧΑΡΙΣΙ ΘΥΕ"

Fostiropoulos had been teaching at Heidelberg University, Free University Berlin, Potsdam University as well as Aristotle University of Thessaloniki (AUTh) in the fields of physical chemistry, soft matter physics and organic photovoltaics. During a four years period from 2011 to 2014 he had been visiting AUTh three months per year where he had been giving lectures in the Ph.D. program of the Department of Physics and collaborated with Stergios Logothetidis and the LTFN - "Laboratory for Thin Films Nanosystems and Nanometrology" in the field of organic electronic materials and devices. Thus, he had the opportunity to experience the financial crisis of his country up close.

In the frame of EU project ROleMak Fostiropoulos had been consultant to the Department of Physics at AUTh.

Invited talks (since 2002)

Institution/conference Host 
19 Nov 2002 Bayreuth University Hans-Werner Schmidt
2003 BASF, Ludwigshafen Karl-Heinrich Hahn
23 Jun 2005 FVS Annual Meeting, Berlin
20 Feb 2006 Light Technology Institut, KIT, Karlsruhe Uli Lemmer
29 Sep 2006 Fritz Haber Institute, Berlin Robert Schlögl
16-18 Jun 2008 IC4N 2008, Halkidiki Efstathios Meletis
9-11 Jul 2008 ISFOE, Halkidiki Stergios Logothetidis
28 Jun - 3 Jul 2009 IC4N 2009, Rodes Efstathios Meletis
8-10 Jul 2009 ISFOE09, Halkidiki Stergios Logothetidis
13-15 Jul 2009 NN09, Thessaloniki Stergios Logothetidis
2010 NCSR DEMOKRITOS, Athens Nick Kanellopoulos
26-29 Jun 2011 IC4N 2011, Crete Efstathios Meletis
30 Jun - 7 Jul 2012 NANOTEXNOLOGY12, Thessaloniki Stergios Logothetidis
16-20 Jun 2013 IC4N 2013, Corfu Efstathios Meletis
6-13 Jul 2013 NANOTEXNOLOGY13, Thessaloniki Stergios Logothetidis
5-12 Jul 2014 NANOTEXNOLOGY14, Thessaloniki Stergios Logothetidis
4-11 Jul 2015 NANOTEXNOLOGY15, Thessaloniki Stergios Logothetidis

Grants and awarded projects

During his early career (1989-1993) Fostiropoulos was granted three times fellowships from the Max Planck Society for his fundamental research on the synthesis of fullerenes and their characterization.

After his scientific come-back to physics in 2001 he was awarded and has been coordinating several German national (BMU, BMBF) as well as Greek-German bilateral (GSRT, BMBF) and EU funded projects ("GR-ELECT", "OrgaPVnet", "SOHyb", "OVPD") with total fund raising of more than eight Million €. Moreover, he also participated in other international projects as a partner. (For more information click "show" in collapsed table below)

table projects/affiliations position 
2013 - 2016 "SMARTONICS" participant
2012 - 2015 Helmholtz Energy Alliance participant
2011 - 2014 EU: "ROleMak" participant
2001 - 2003 BMU: "Polymer Solar Cells" participant
2001 - 2003 BMU: "Organic Solar Cells" participant
2014 - 2015 (bilateral Greek/German) GSRT/BMBF: "GR-ELECT" German coordinator
2009 - 2012 BMBF: "SOHyb" coordinator
2006 - 2009 EU Coordination Action: "OrgaPVnet" coordinator of German affiliates
2003 - 2007 BMU: "Organic Solar Cells with OVPD" coordinator
1993 - 1993 Max Planck Group: Dust in star forming regions, Jena University Max Planck Fellow
1992 - 1992 Max Planck Institute for Nuclear Physics, Heidelberg Max Planck Fellow
1989 - 1992 Max Planck Institute for Nuclear Physics, Heidelberg Max Planck Ph.D. Stipend

International events

Since 2012 Fostiropoulos is member of the International Scientific Committee of the annual event NANOTEXNOLOGY organized by the Aristotle University of Thessaloniki (coord. Stergios Logothetidis). It takes place every July in the city of Thessaloniki, Greece.

In 2012 Fostiropoulos and Chungyang Jia, University of Electronic Science and Technology of China, co-organized "The Sino-German Symposium on Organic Photovoltaic Materials and Organic Solar Cells” in Chengdu, Sichuan, China.[25] In the frame of the EU Coordination Action "OrgaPVNet"[26] he represented 20 German affiliates together with Andreas Hinsch, Fraunhofer Institute for Solar Energy Systems ISE. They co-organized the "OrgaPVNet: National Workshop of German Affiliates", 22–23 January 2007, at the former Hahn-Meitner-Institut Berlin.

Editorial

G. Eckel & K. Fostiropoulos (Editors), "Institute for Media Communication, Accomplishments in depth – Periode 1993-1999" (GMD 1999)

References

  1. 1 2 "Dusty Objects in the Universe, September 1989, Capri, Italy", conference proceedings, page 89-93, "Search for the UV and IR spectra of C60 in laboratory-produced carbon dust"
  2. 1 2 3 Journal of BGRCI, page 14:"Fostiropoulos... konnte schließlich erstmals einige Gramm reines Fulleren herstellen."
  3. 1 2 C60: Buckminsterfullerene
  4. ↑ Fostiropoulos et al., 2002 SPIE conference proceedings, "Preparation and investigation of phthalocyanine/C60 solar cells"
  5. 1 2 GMD's experimental low band width connectivity internet teaching platform for transatlantic courses
  6. ↑ 2004, the "Greek" year: UEFA European Championship, and Games of the XXVIII Olympiad
  7. ↑ William Weltner jr. "Spectroscopy of Carbon Vapor Condensed in Rare‐Gas..."
  8. 1 2 Bernd Wagner had finished his studies as senior high school teacher and has been working since then as physics teacher in the Cologne area. He did not co-author any of the three C60 publications of 1990 and was not considered when the C60 synthesis had been filed with an US patent office.
  9. ↑ "Verunreinigungen durch Pumpenöl"
  10. ↑ "It's junk!" Wolfgang Krätschmer in BBC HORIZON episode "Molecules with sunglasses", 20/01/1992, BBC_LSFA479X
  11. ↑ The infrared and ultraviolet absorption spectra of laboratory-produced carbon dust: evidence for the presence of the C60 molecule
  12. ↑ Data from Andreas Bart and Werner Marx
  13. ↑ First thin film chromatography studies on the fullerene mixture Fostiropoulos began at Max Planck Institute for Medical Research January 1990 together with former students of his in the group of Heinz August Staab the then institute's director and president of the Max Planck Society
  14. ↑ Prof. Werner Kühlbrandt, Director at Max Planck Institute of Biophysics
  15. ↑ ...that C60 might survive in the general interstellar medium (probably as the ion C60+)... http://www.kroto.info/wp-content/uploads/2015/05/HWKroto-1987-discussing-the-possibiliy-of-C60-and-its-analogues-in-space-and-as-DIB-carriers.pdf
  16. ↑ "Detection of two interstellar absorption bands coincident with spectral features of C60+"
  17. 1 2 3 "Solid C60 - a new form of carbon"
  18. ↑ "C60 - eine neue Form des Kohlenstoffs" (Ph.D. thesis 1989-1991) submitted to the Faculty of Physics and Astronomy at Heidelberg University by Konstantinos Fostiropoulos, graduated 12 February 1992 ("Magna cum Laude"). First assessor and supervisor Prof. Hugo Fechtig, second assessor Prof. Walter Roedel.
  19. ↑ Prof. Hugo Fechtig: "... Mr. Fostiropoulos has performed the work with great personal commitment... and contributed his own original ideas. For the C60 publications that caused world-wide big sensation he played an extensive part..." (Fostiropoulos' Ph.D. assessment)
  20. ↑ Harry Kroto about those who deny the existence of C60 in space
  21. ↑ page 42 of ISSPIC-5 in Konstanz in 1990: Announcements of the C60 preparation and its structure confirmation
  22. ↑ Harry's homepage
  23. ↑ Plastic Solar Cells
  24. ↑ NREL Best Research-Cell Efficiencies, category Emerging PV, Organic cells (various types): 2001-2003 University Linz 2.5% efficiency (with polymer absorber)
  25. ↑ The Sino-German Symposium in Chengdu, Sichuan, China, 27.05 – 31.05.2012, on “Organic Photovoltaic Materials and Organic Solar Cells”
  26. ↑ CORDIS: OrgaPVNet
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