Pekka Pyykkö

Pekka Pyykkö (October 12, 1941)^[1] is a Finnish professor of Chemistry at the University of Helsinki.^[1] From 2009–2012, he was the chairman of the International Academy of Quantum Molecular Science. He is known for his extension to the periodic table of elements, called Pyykkö model.

Pyykkö model

Pekka Pyykkö predicts that the orbital shells will fill up in this order:

• 8s,
• 5g,
• the first two spaces of 8p,
• 6f,
• 7d,
• 9s,
• the first two spaces of 9p,
• the rest of 8p.^[2]

He also suggests that period 8 be split into three parts:

• 8a, containing 8s,
• 8b, containing the first two elements of 8p,
• 8c, containing 7d and the rest of 8p.^[2]

Pyykkö model
	Displaced elements are in boldface
8	119 Uue	120 Ubn	121 Ubu	122 Ubb	123 Ubt	124 Ubq	125 Ubp	126 Ubh	127 Ubs	128 Ubo	129 Ube	130 Utn	131 Utu	132 Utb	133 Utt	134 Utq	135 Utp	136 Uth	137 Uts	138 Uto	141 Uqu	142 Uqb	143 Uqt	144 Uqq	145 Uqp	146 Uqh	147 Uqs	148 Uqo	149 Uqe	150 Upn	151 Upu	152 Upb	153 Upt	154 Upq	155 Upp	156 Uph	157 Ups	158 Upo	159 Upe	160 Uhn	161 Uhu	162 Uhb	163 Uht	164 Uhq	139 Ute	140 Uqn	169 Uhe	170 Usn	171 Usu	172 Usb
9	165 Uhp	166 Uhh																																											167 Uhs	168 Uho
	s-block		g-block																		f-block														d-block										p-block

The compact version.^[2]

Pekka Pyykkö successfully predicted the possibility of a chemical bond between gold and the noble gas xenon, which is usually extremely inert; this bond is known to occur in the cationic complex tetraxenonogold(II) (AuXe2+
4). He also successfully predicted the possibility of a gold–carbon triple bond.^[3]

References

1. "Curriculum vitae". chem.helsinki.fi. 2012-04-25. Retrieved 2012-05-28.
2. Pyykkö, Pekka (2011). "A suggested periodic table up to Z≤ 172, based on Dirac–Fock calculations on atoms and ions". Physical Chemistry Chemical Physics. 13 (1): 161–8. Bibcode:2011PCCP...13..161P. doi:10.1039/c0cp01575j. PMID 20967377.
3. Scientific American June 2013, "Cracks in the Periodic Table". p. 72.